Strain-activated light-induced halide segregation in mixed-halide perovskite solids.

ABSTRACT: Light-induced halide segregation limits the bandgap tunability of mixed-halide perovskites for tandem photovoltaics. Here we report that light-induced halide segregation is strain-activated in MAPb(I_1-xBr_x)₃ with Br concentration below approximately 50%, while it is intrinsic for Br concentration over approximately 50%. Free-standing single crystals of CH₃NH₃Pb(I_0.65Br_0.35)₃ (35%Br) do not show halide segregation until uniaxial pressure is applied. Besides, 35%Br single crystals grown on lattice-mismatched substrates (e.g. single-crystal CaF₂) show inhomogeneous segregation due to heterogenous strain distribution. Through scanning probe microscopy, the above findings are successfully translat

SUBMITTER: Zhao Y 

PROVIDER: S-EPMC7730187 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature