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Amine-borane complex-initiated SF5Cl radical addition on alkenes and alkynes.

ABSTRACT: The SF5Cl radical addition on unsaturated compounds was performed using an air-stable amine-borane complex as the radical initiator. This method showed to be complementary to the classic Et3B-mediated SF5Cl addition on alkenes and alkynes. A total of seven alkene and three alkyne derivatives were tested in the reaction, with yields ranging from 3% to 85%.

SUBMITTER: Gilbert A 

PROVIDER: S-EPMC7753108 | biostudies-literature |

REPOSITORIES: biostudies-literature

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