A Chatt-Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia.

ABSTRACT: With [Mo(N₂ )(P₂ ^Me PP₂ ^Ph )] the first Chatt-type complex with one coordination site catalytically converting N₂ to ammonia is presented. Employing SmI₂ as reductant and H₂ O as proton source 26 equivalents of ammonia are generated. Analogous Mo⁰ -N₂ complexes supported by a combination of bi- and tridentate phosphine ligands are catalytically inactive under the same conditions. These findings are interpreted by analyzing structural and spectroscopic features of the employed systems, leading to the conclusion that the catalytic activity of the title complex is due to the strong activation of N₂ and the unique topology of the pentadentate tetrapodal (pentaPod) ligand P

SUBMITTER: Engesser TA 

PROVIDER: S-EPMC7756349 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature