Molecular Zinc Hydride Cations [ZnH]+ : Synthesis, Structure, and CO2 Hydrosilylation Catalysis.
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ABSTRACT: Protonolysis of [ZnH2 ]n with the conjugated Brønsted acid of the bidentate diamine TMEDA (N,N,N',N'-tetramethylethane-1,2-diamine) and TEEDA (N,N,N',N'-tetraethylethane-1,2-diamine) gave the zinc hydride cation [(L2 )ZnH]+ , isolable either as the mononuclear THF adduct [(L2 )ZnH(thf)]+ [BArF 4 ]- (L2 =TMEDA; BArF 4 - =[B(3,5-(CF3 )2 -C6 H3 )4 ]- ) or as the dimer [{(L2 )Zn)}2 (μ-H)2 ]2+ [BArF 4 ]- 2 (L2 =TEEDA). In contrast to [ZnH2 ]n , the cationic zinc hydrides
SUBMITTER: Ritter F
PROVIDER: S-EPMC7756573 | biostudies-literature | 2020 Dec
REPOSITORIES: biostudies-literature
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