Cation Distributions and Magnetic Properties of Ferrispinel MgFeMnO₄.

ABSTRACT: The crystal structure and magnetic properties of the cubic spinel MgFeMnO₄ were studied by using a series of in-house techniques along with large-scale neutron diffraction and muon spin rotation spectroscopy in the temperature range between 1.5 and 500 K. The detailed crystal structure is successfully refined by using a cubic spinel structure described by the space group Fd3̅m. Cations within tetrahedral A and octahedral B sites of the spinel were found to be in a disordered state. The extracted fractional site occupancies confirm the presence of antisite defects, which are of importance for the electrochemical performance of MgFeMnO₄ and related battery materials. Neutron diffraction and muon spin spectroscopy reveal a ferrimagnetic order below T_C = 394.2 K, having a collinear spin arrangement with antiparallel spins at the A and B sites, respectively. Our findings provide new and improved understanding of the fundamental properties of the ferrispinel materials and of their potential applications within future spintronics and battery devices.

SUBMITTER: Matsubara N 

PROVIDER: S-EPMC7759007 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature