Different Benzendicarboxylate-Directed Structural Variations and Properties of Four New Porous Cd(II)-Pyridyl-Triazole Coordination Polymers.

ABSTRACT: Four new different porous crystalline Cd(II)-based coordination polymers (CPs), i. e., [Cd(mdpt)₂]·2H₂O (1), [Cd₂(mdpt)₂(m-bdc)(H₂O)₂] (2), [Cd(Hmdpt)(p-bdc)]·2H₂O (3), and [Cd₃(mdpt)₂(bpdc)₂]·2.5NMP (4), were obtained successfully by the assembly of Cd(II) ions and bitopic 3-(3-methyl-2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (Hmdpt) in the presence of various benzendicarboxylate ligands, i.e., 1,3/1,4-benzenedicarboxylic acid (m-H₂bdc, p-H₂bdc) and biphenyl-4,4'-bicarboxylate (H₂bpdc). Herein, complex 1 is a porous 2-fold interpenetrated four-connected 3D NbO topological fr

SUBMITTER: Zhao Y 

PROVIDER: S-EPMC7773847 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature