Performance of a NiFe₂O₄@Co Core-Shell Fischer-Tropsch Catalyst: Effect of Low Temperature Reduction.

ABSTRACT: In situ TEM gas-cell imaging and spectroscopy with in situ XRD have been applied to reveal morphological changes in NiFe₂O₄@Co₃O₄ core-shell nanoparticles in hydrogen. The core-shell structure is retained upon reduction under mild conditions (180 °C for 1 h), resulting in a partially reduced shell. The core-shell structure was retained after exposing these reduced NiFe₂O₄@Co₃O₄ core-shell nanoparticles to Fischer-Tropsch conditions at 230 °C and 20 bar. Slightly harsher reduction (230 °C, 2 h) resulted in restructuring of the NiFe₂O₄@Co₃O₄ core-shell nanoparticles to form cobalt islands in addition to partially reduced NiFe₂O₄. NiFe₂

SUBMITTER: Govender A 

PROVIDER: S-EPMC7774086 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature