Crystal and mol-ecular structures of di-chlorido-palladium(II) containing 2-methyl- or 2-phenyl-8-(diphenyphosphan-yl)quinoline.

ABSTRACT: The crystal structures of di-chlorido-palladium(II) complexes bearing 2-methyl- and 2-phenyl-8-(di-phenyl-phosphan-yl)quinoline, namely, di-chlorido-[8-(di-phenyl-phosphan-yl)-2-methyl-quinoline-κ² N,P]palladium(II), [PdCl₂(C₂₂H₁₈NP)] (1) and di-chlorido-[8-(di-phenyl-phosphan-yl)-2-phenyl-quinoline-κ² N,P]palladium(II), [PdCl₂(C₂₇H₂₀NP)] (2), were analyzed and compared to that of the 8-(di-phenyl-phosphan-yl)quinoline (PQ^H) analogue (3). In all three complexes, the phosphanyl-quinoline moiety acts as a bidentate P,N-donating chelate ligand. In the PQ^H complex (3), the Pd^II center has a typical planar coordin

SUBMITTER: Mori M 

PROVIDER: S-EPMC7784056 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature