Comparison of mol-ecular structures of cis-bis-[8-(di-methyl-phosphan-yl)quinoline]-nickel(II) and -platinum(II) complex cations.

ABSTRACT: The crystal structures of the complexes (SP-4-2)-cis-bis-[8-(di-methyl-phosphan-yl)quinoline-κ² N,P]nickel(II) bis-(perchlorate) nitro-methane monosolvate, [Ni(C₁₁H₁₂NP)₂](ClO₄)₂·CH₃NO₂ (1), and (SP-4-2)-cis-bis-[8-(di-methyl-phos-phan-yl)quinoline-κ² N,P]platinum(II) bis-(tetra-fluoro-borate) aceto-nitrile monosolvate, [Pt(C₁₁H₁₂NP)₂](BF₄)₂·C₂H₃N (2), are reported. In both complex cations, two phosphanyl-quinolines act as bidentate P,N-donating chelate ligands and form the mutually cis configuration in the square-planar coordination

SUBMITTER: Mori M 

PROVIDER: S-EPMC7784645 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature