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Crystal structure of the coordination polymer catena-poly[[bis-[hy-droxy(phen-yl)acetato-κ² O ¹,O ²]zinc(II)]-μ₂-1,2-bis-(pyridin-4-yl)ethane-κ² N:N'].

ABSTRACT: In the title polymeric Zn^II compound, [Zn(C₈H₇O₃)₂(C₁₂H₁₂N₂)] _n , the Zn cation is coordinated by two N atoms from 1,2-bis-(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy-droxy(phen-yl)acetate] anions in a slightly distorted octa-hedral coordination geometry. The 1,2-bis-(pyridin-4-yl)ethane unit bridges two Zn^II cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O-H⋯O and weak C-H ⋯O hydrogen bonds, with C-H ⋯ π inter-actions and π-π inter-actions also being present. The centroid-centroid distance between the phenyl ring of the mandelate group and the 1,2-bis-(pyridine-4-yl)ethane moi

SUBMITTER: Fwu Ming S

PROVIDER: S-EPMC7784659 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of the coordination polymer catena-poly[[bis-[hy-droxy(phen-yl)acetato-κ² O ¹,O ²]zinc(II)]-μ₂-1,2-bis-(pyridin-4-yl)ethane-κ² N:N'].

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Crystal structure of the coordination polymer catena-poly[[bis-[hy-droxy(phen-yl)acetato-κ2 O 1,O 2]zinc(II)]-μ2-1,2-bis-(pyridin-4-yl)ethane-κ2 N:N'].

OmicsDI is part of the ELIXIR infrastructure

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Crystal structure of the coordination polymer catena-poly[[bis-[hy-droxy(phen-yl)acetato-κ² O ¹,O ²]zinc(II)]-μ₂-1,2-bis-(pyridin-4-yl)ethane-κ² N:N'].