Study of Tetrahydroxylated Anthraquinones-Potential Tool to Assess Degradation of Anthocyanins Rich Food.

ABSTRACT: Degradation of anthocyanins involves scission of the flavonoid skeleton yielding 2,4,6-trihydroxybenzaldehyde (phloroglucinaldehyde, PGA) and a phenolic acid. However, the process is not finished with the formation of PGA, as the consequent condensation of two PGA molecules providing colored hydroxylated anthraquinones was observed for the first time. This process was studied using a combination of preparative column chromatography, nuclear magnetic resonance, liquid chromatography/high resolution tandem mass spectrometry (LC/HRMS2), and quantum calculations using density functional theory. 1,3,5,7-tetrahydroxyanthraquinone (anthrachrysone) and its isomers were found to rise during heating (95 °C) in a buffered PGA model solution (phosphate buffer, pH 7). These compounds were detected in h

SUBMITTER: Kucera L 

PROVIDER: S-EPMC7792584 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature