One-Step Synthesis of Eu3+-Modified Cellulose Acetate Film and Light Conversion Mechanism.

ABSTRACT: A CA-Eu(III) complex was synthesized by the coordination reaction of cellulose acetate (CA) and Eu3+ to obtain a CA-Eu light conversion film. This product was then doped with Tb(III) to sensitize the luminescence of Eu3+, which could functionalize the CA film. FTIR and XPS showed that the oxygen atoms in C=O, C-O (O=C-O), and O-H were involved in the complexation with Eu3+ and formed a Eu-O bond. SEM revealed that Eu3+ filled in the pores of the CA film. By changing the experimental conditions, the best fluorescence performance was obtained at the CA: Eu3+ ratio of 3:1 with a reaction time of 65 min. The energy transfer between Tb3+-Eu3+ could be realized by doping Tb3+ to enhance the luminescence of Eu3+. The best fluorescence performance of the CA-Eu-Tb light conversion film was at a Eu3

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC7795846 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature