[Fe(CN)₅NO]^2--Based MOIFs for Adsorption of Organic Pollutants and as a Self-Rotatory Motor.

ABSTRACT: Herein, we report metal-organic ionic frameworks (MOIFs; an ionic product of an anionic complex and an organic cationic head group) for the adsorption of toxic organic pollutants and as a self-rotatory motor. MOIFs were synthesized via the ion-exchange mechanism in water (without use of any toxic organic solvent) using Na₂[Fe(CN)₅NO] and [C _n H_2n+1N⁺(CH₃)₃]₂ and characterized through small-angle X-ray scattering (SAXS), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) techniques. Thermal gravimetric (TGA/DTA) and differential scanning calorimetric (DSC) studies of MOIFs have informed their activation energy, enthalpies of crystallization/melting, and specific heat capacity (S

SUBMITTER: Ameta RK 

PROVIDER: S-EPMC7807800 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature