Nontargeted mass-spectral detection of chloroperfluoropolyether carboxylates in New Jersey soils.

ABSTRACT: The toxicity and environmental persistence of anthropogenic per- and poly-fluoroalkyl substances (PFAS) are of global concern. To address legacy PFAS concerns in the United States, industry developed numerous replacement PFAS that commonly are treated as confidential information. To investigate the distribution of PFAS in New Jersey, soils collected from across the state were subjected to nontargeted mass-spectral analyses. Ten chloroperfluoropolyether carboxylates were tentatively identified, with at least three congeners in all samples. Nine congeners are ≥(CF₂)₇ Distinct chemical formulas and structures, as well as geographic distribution, suggest airborne transport from an industrial source. Lighter congeners dispersed more widely than heavier congeners, with the

SUBMITTER: Washington JW 

PROVIDER: S-EPMC7814412 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature