Stress relaxation in symmetric ring-linear polymer blends at low ring fractions.

ABSTRACT: We combine linear viscoelastic measurements and modelling in order to explore the dynamics of blends of the same-molecular-weight ring and linear polymers in the regime of the low volume fraction (0.3 or lower) of the ring component. The stress relaxation modulus is affected by the constraint release (CR) of both rings and linear components due to the motion of linear chains. We develop a CR-based model of ring-linear blends that predicts the stress relaxation function in the low fraction regime of ring component in excellent agreement with experiments. Rings trapped by their entanglements with linear chains can only relax by linear-chain-induced constraint release, resulting in much slower relaxation of rings than of linear chains. The relative viscosity η ( ϕ R * ) / η L of the b

SUBMITTER: Parisi D 

PROVIDER: S-EPMC7839933 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature