Addition of Sodium Additives for Improved Performance of Water-Gas Shift Reaction over Ni-Based Catalysts.

ABSTRACT: The effect of Na loading on water-gas shift reaction (WGSR) activity of Ni@TiO _x -XNa (X = 0, 0.5, 1, 2, and 5 wt %) catalysts has been investigated. Herein, we report sodium-modified Ni@TiO _x catalysts (denoted as Ni@TiO _x -XNa) derived from Ni₃Ti₁-layered double hydroxide (Ni₃Ti₁-LDH) precursor. The optimized Ni@TiO _x -1Na catalyst exhibits enhanced catalytic performance toward WGSR at relatively low temperature and reaches an equilibrium CO conversion at 300 °C, which is much superior to those for most of the reported Ni-based catalysts. The H₂-temperature-programmed reduction (H₂-TPR) result demonstrates that the Ni@TiO _x

SUBMITTER: Li N 

PROVIDER: S-EPMC7841924 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature