Ion adsorption-induced reversible polarization switching of a van der Waals layered ferroelectric.

ABSTRACT: Solid-liquid interface is a key concept of many research fields, enabling numerous physical phenomena and practical applications. For example, electrode-electrolyte interfaces with electric double layers have been widely used in energy storage and regulating physical properties of functional materials. Creating a specific interface allows emergent functionalities and effects. Here, we show the artificial control of ferroelectric-liquid interfacial structures to switch polarization states reversibly in a van der Waals layered ferroelectric CuInP₂S₆ (CIPS). We discover that upward and downward polarization states can be induced by spontaneous physical adsorption of dodecylbenzenesulphonate anions and N,N-diethyl-N-methyl-N-(2-methoxyethyl)-ammonium cations, respectively

SUBMITTER: Xu DD 

PROVIDER: S-EPMC7844287 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature