Daylight-activated fumigant detoxifying nanofibrous membrane based on thiol-ene click chemistry.

ABSTRACT: Daylight-activated detoxifying nanofibrous membranes (LDNMs) are fabricated by grafting benzophenone-3,3',4,4'-tetracarboxylic dianhydride (BD) and biological thiols successively on poly(vinyl alcohol-co-ethylene) (EVOH) nanofibrous membrane. Taking the merits of photoactivity of BD, high-reactivity of biological thiols, and high specific surface area and porosity of the nanofibrous membrane, 1,3-dichloropropene (1,3-D) can be efficiently detoxified on the LDNMs under daylight irradiation via a thiol-ene click reaction. The detoxification function of the LDNMs is "switched on" by light irradiation and continues by following a cascade of chemical attacks of thiyl radicals formed during the photoexcitation process. The resultant LDNMs present rapid detoxification rate (i.e., t_1/2

SUBMITTER: Tang P 

PROVIDER: S-EPMC7855875 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature