Ge-Fe Carbonyl Cluster Compounds: Ionic Liquids-Based Synthesis, Structures, and Properties.

ABSTRACT: Nine Ge-Fe carbonyl cluster compounds are prepared via ionic liquids-based synthesis. This includes the novel compounds [EMIm][Fe(CO)₃ I(GeI₃ )], [EHIm][Fe(CO)₃ I(GeI₃ )], [BMIm][GeI₂ {Fe(CO)₄ }₂ (μ-I)][AlCl₄ ]₂ , [GeI₂ {Fe(CO)₄ }₂ (μ-I)][Fe(AlBr₄ )₃ ], [BMIm]₂ [(FeI₂ )_0.75 {Fe(CO)₂ I(GeI₃ )₂ }₂ ], and [EHIm][Fe(CO)₄ (GeI₂ )₂ Fe(CO)₃ GeI₃ ] as well as the previously reported compounds (Fe(CO)₄ (GeI₃ )₂ , FeI₄ {GeI₃ Fe(CO)₃ }₂ , and G

SUBMITTER: Wolf S 

PROVIDER: S-EPMC7874258 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature