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Electrochemical Detection of Hydrazine by Carbon Paste Electrode Modified with Ferrocene Derivatives, Ionic Liquid, and CoS₂-Carbon Nanotube Nanocomposite.

ABSTRACT: The electrocatalytic performance of carbon paste electrode (CPE) modified with ferrocene-derivative (ethyl2-(4-ferrocenyl[1,2,3]triazol-1-yl)acetate), ionic liquid (n-hexyl-3-methylimidazolium hexafluorophosphate), and CoS₂-carbon nanotube nanocomposite (EFTA/IL/CoS₂-CNT/CPE) was investigated for the electrocatalytic detection of hydrazine. CoS₂-CNT nanocomposite was characterized by field emission scanning electron microscopy, X-ray powder diffraction, and transmission electron microscopy. According to the results of cyclic voltammetry, the EFTA/IL/CoS₂-CNT-integrated CPE has been accompanied by greater catalytic activities for hydrazine oxidation compared to the other electrodes in phosphate buffer solution at a pH 7.0 as a result of the synergistic impact of fused ferrocene-derivative, IL, and nanocomposite. The sensor responded linearly with increasing concentration of hydrazine from 0.03 to 500.0 μM with a higher sensitivity (0.073 μA μM^-1) and lower limit of detection (LOD, 0.015 μM). Furthermore, reasonable reproducibility, lengthy stability, and excellent selectivity were also attained for the proposed sensor. Finally, EFTA/IL/CoS₂-CNT/CPE was applied for the detection of hydrazine in water samples, and good recoveries varied from 96.7 to 103.0%.

SUBMITTER: Tajik S

PROVIDER: S-EPMC7905812 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Electrochemical Detection of Hydrazine by Carbon Paste Electrode Modified with Ferrocene Derivatives, Ionic Liquid, and CoS2-Carbon Nanotube Nanocomposite.

Tajik Somayeh S Beitollahi Hadi H Hosseinzadeh Rahman R Aghaei Afshar Abbas A Varma Rajender S RS Jang Ho Won HW Shokouhimehr Mohammadreza M

ACS omega 20210208 7

The electrocatalytic performance of carbon paste electrode (CPE) modified with ferrocene-derivative (ethyl2-(4-ferrocenyl[1,2,3]triazol-1-yl)acetate), ionic liquid (n-hexyl-3-methylimidazolium hexafluorophosphate), and CoS2-carbon nanotube nanocomposite (EFTA/IL/CoS2-CNT/CPE) was investigated for the electrocatalytic detection of hydrazine. CoS2-CNT nanocomposite was characterized by field emission scanning electron microscopy, X-ray powder diffraction, an ...[more]

PMID: 33644570

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Project description:Selenite (Se4+), a significant source of water pollution above the permissible limits, is considered a valuable metal by environmentalists. In this study, we described a novel electrochemical sensor that utilized a carbon paste electrode (CPE) that was modified using multiwall carbon nanotubes (MWCNTs) and poly(1-aminoanthraquinone) (p-AAQ) for finding Se4+ in water samples. Electrochemical quantification of Se4+ depends on the formation of a selective complex (piaselenol) with p-AAQ. In this work, we prepared a CPE modified by physical embedding of MWCNTs and 1-aminoanthraquione (AAQ), while the polymer film was formed by anodic polymerization of AAQ by applying a constant potential of 0.75 V in 0.1 M HCl for 20 s followed by cyclic voltammetry (CV) from -0.2 to 1.4 V for 20 cycles. The modified CPE was used for differential pulse voltammetry (DPV) of Se4+ in 0.1 M H2SO4 from 0 to 0.4 V with a characteristic peak at 0.27 V. Further, the proposed sensor was characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and electrochemical impedance spectroscopy (EIS). The analytical conditions regarding the electrode performance and voltammetric measurements were optimized, with the accumulation time and potential, supporting electrolyte, differential-pulse period/time, and amplitude. The EIS results indicated that the p-AAQ/MWCNTs-modified CPE sensor (p-AAQ/MWCNTs/CPE) that also exhibited low charge-transfer resistance (R ct) toward the anodic stripping of Se4+, exhibited good analytical performance toward different concentrations of Se4+ in a linear range of 5-50 μg L-1 Se4+ with a limit of determination (LOD) of 1.5 μg L-1 (3σ). Furthermore, differential-pulse voltammetry was employed to determine different concentrations of Se4+ in a linear range of 1-50 μg L-1 Se4+, and an LOD value of 0.289 μg L-1 was obtained. The proposed sensor demonstrated good precision (relative standard deviation = 4.02%) at a Se4+ concentration of 5 μg L-1. Moreover, the proposed sensor was applied to analyze Se4+ in wastewater samples that were spiked with Se, and it achieved good recovery values.

Dataset Information

Electrochemical Detection of Hydrazine by Carbon Paste Electrode Modified with Ferrocene Derivatives, Ionic Liquid, and CoS₂-Carbon Nanotube Nanocomposite.

Publications

Electrochemical Detection of Hydrazine by Carbon Paste Electrode Modified with Ferrocene Derivatives, Ionic Liquid, and CoS<sub>2</sub>-Carbon Nanotube Nanocomposite.

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