Mixed Matrix Membranes Based on Fluoropolymers with m- and p-Terphenyl Fragments for Gas Separation Applications.

ABSTRACT: Novel mixed matrix membranes (MMMs) based on fluoropolymers with m- and p-terphenyl fragments and NaX zeolites were prepared. The fluoropolymers were synthesized by a one-pot, room-temperature, metal-free superacid-catalyzed stoichiometric and nonstoichiometric step polymerization of 2,2,2-trifluoroacetophenone with two multiring aromatic nonactivated hydrocarbons (p-terphenyl and m-terphenyl). MMMs were characterized by scanning electron microscopy (SEM) and infrared (Fourier transform infrared (FTIR)) spectroscopy and used in gas permeability tests. SEM analysis showed interfacial voids in MMMs prepared in N-methyl-2-pyrrolidone (NMP), The interfacial adhesion in the polymer-zeolite system was considerably improved when chloroform was used as a solvent.

SUBMITTER: Hernandez-Martinez H 

PROVIDER: S-EPMC7905937 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature