Laser ablation synthesis of metal-doped gold clusters from composites of gold nanoparticles with metal organic frameworks.

ABSTRACT: Metal-doped gold clusters, mainly cages, are receiving rapidly increasing attention due to their tunable catalytic properties. Their synthesis is mostly based on complex procedures, including several steps. In this work, via adsorption of gold nanoparticles (AuNPs) from aqueous solution to MOF (metal organic frameworks) of M = Co, Cu, Ni, and Zn with various linkers the {AuNPs, MOF} composites were prepared. These composites were used for laser ablation synthesis (LAS) using a common mass spectrometer. Several series of positively and negatively charged Au_mM_n^+/- clusters were observed in mass spectra and their stoichiometry (m = 1-35, n = 1-5) was determined. For each dopant (Co, Cu, Ni, and Zn) ~ 50 different clusters were identified in positive, as well a

SUBMITTER: Pecinka L 

PROVIDER: S-EPMC7907063 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature