A Long-Term Stable Sensor Based on Fe@PCN-224 for Rapid and Quantitative Detection of H2O2 in Fishery Products.

ABSTRACT: Hydrogen peroxide (H2O2) has been reported to be used for the illegal treatment of fishery products in order to obtain "fake" freshness. Residues of H2O2 in food may be of toxicology concern. In this study, a nonenzymatic sensor was developed based on Fe@PCN-224 metal-organic frameworks wrapped by Nafion to detect H2O2 concentration. The hybrid structure of Fe@PCN-224 was fabricated by incorporated free FeIII ions into the center of PCN-224, which was ultra-stable due to the strong interactions between Zr6 and the carboxyl group. Scanning electron spectroscopy images exhibited that Nafion sheets crossed together on the surface of Fe@PCN-224 nanoparticles to form a hierarchical and coherent structure for efficient electron transfer. Electrochemical investigations showed that the Fe@PCN-224/

SUBMITTER: Hu P 

PROVIDER: S-EPMC7918592 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature