One-Dimensional Organic-Inorganic Material (C₆H₉N₂)₂BiCl₅: From Synthesis to Structural, Spectroscopic, and Electronic Characterizations.

ABSTRACT: The new organic-inorganic compound (C₆H₉N₂)₂BiCl₅ (I) has been grown by the solvent evaporation method. The one-dimensional (1D) structure of the allylimidazolium chlorobismuthate (I) has been determined by single crystal X-ray diffraction. It crystallizes in the centrosymmetric space group C2/c and consists of 1-allylimidazolium cations and (1D) chains of the anion BiCl₅^2-, built up of corner-sharing [BiCl₆^3-] octahedra which are interconnected by means of hydrogen bonding contacts N/C-H⋯Cl. The intermolecular interactions were quantified using Hirshfeld surface analysis and the enrichment ratio established that the most important role in the stability of the crystal structure was provided b

SUBMITTER: Ferjani H 

PROVIDER: S-EPMC7922144 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature