Mercury Reduction by Nanoparticulate Vivianite.

ABSTRACT: Mercury (Hg) is a toxic trace element of global environmental concern which has been increasingly dispersed into the environment since the industrial revolution. In aquatic and terrestrial systems, Hg can be reduced to elemental Hg (Hg⁰) and escape to the atmosphere or converted to methylmercury (MeHg), a potent neurotoxin that accumulates in food webs. Fe^II-bearing minerals such as magnetite, green rusts, siderite, and mackinawite are recognized Hg^II reducers. Another potentially Hg-reducing mineral, which commonly occurs in Fe- and organic/P-rich sediments and soils, is the ferrous iron phosphate mineral vivianite (Fe^II₃(PO₄)₂·8H₂O), but its reaction with Hg^II has not been studied to date.

SUBMITTER: Etique M 

PROVIDER: S-EPMC7931808 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature