Ultrafast spectroscopy reveals singlet fission, ionization and excimer formation in perylene film.

ABSTRACT: Singlet exciton fission (SF) is a spin-allowed process whereby two triplet excitons are created from one singlet exciton. This phenomenon can offset UV photon energy losses and enhance the overall efficiency in photovoltaic devices. For this purpose, it requires photostable commercially available SF materials. Excited state dynamics in pure perylene film, ease of commercial production, is studied by time-resolved fluorescence and femtosecond transient absorption techniques under different photoexcitation energies. In film, polycrystalline regions contain perylene in H-type aggregate form. SF takes place from higher excited states of these aggregates in ultrafast time scale < 30 fs, reaching a triplet formation quantum yield of 108%. Moreover, at λ_ex = 450 nm singlet fission was

SUBMITTER: Ni W 

PROVIDER: S-EPMC7933242 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature