Influence of Geometry on Thin Layer and Diffusion Processes at Carbon Electrodes.

ABSTRACT: The geometric structure of carbon electrodes affects their electrochemical behavior, and large-scale surface roughness leads to thin layer electrochemistry when analyte is trapped in pores. However, the current response is always a mixture of both thin layer and diffusion processes. Here, we systematically explore the effects of thin layer electrochemistry and diffusion at carbon fiber (CF), carbon nanospike (CNS), and carbon nanotube yarn (CNTY) electrodes. The cyclic voltammetry (CV) response to the surface-insensitive redox couple Ru(NH₃)₆^3+/2+ is tested, so the geometric structure is the only factor. At CFs, the reaction is diffusion-controlled because the surface is smooth. CNTY electrodes have gaps between nanotubes that are about 10 μm deep, comparab

SUBMITTER: Cao Q 

PROVIDER: S-EPMC7937503 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature