Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.

ABSTRACT: We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm³ (STP) cm^-3 at 298 K and 5-80 bar.

SUBMITTER: Shao K 

PROVIDER: S-EPMC7953312 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature