A Simple Turn-off Schiff Base Fluorescent Sensor for Copper (II) Ion and Its Application in Water Analysis.

ABSTRACT: An aniline-functionalized naphthalene dialdehyde Schiff base fluorescent probe L with aggregation-induced enhanced emission (AIEE) characteristics was synthesized via a simple one-step condensation reaction and exhibited excellent sensitivity and selectivity towards copper(II) ions in aqueous media with a fluorescence " turn-off " phenomenon. The detection limit of the probe is 1.64 × 10^-8 mol·L^-1. Furthermore, according to the results of the UV-vis/fluorescence titrations, Job's plot method and ¹H-NMR titrations, a 1:2 stoichiometry was identified. The binding constant between L and Cu²⁺ was calculated to be K_a = 1.222 × 10³. In addition, the AIEE fluorescent probe L could be applied to detection

SUBMITTER: Zhang X 

PROVIDER: S-EPMC7956479 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature