Browse
Submit Data
Databases
API
Help

Dataset Information

57 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Structure-Property Relationship of Polymerized Ionic Liquids for Solid-State Electrolyte Membranes.

ABSTRACT: Eight new polymerized ammonium-based ionic liquids were prepared as thin membrane films and evaluated within the scope of their usage in lithium-ion batteries. The focus of this work is to get a better understanding of the influence of structural modifications of the monomers on the polymerized materials. Further, different concentrations of a lithium-ion conducting salt were applied in order to receive an optimized combination of monomer structure and lithium salt concentration. It was found that an increased side chain length of the studied ammonium-based polymerized ionic liquids leads to a reduction in glass transition temperatures and increased ionic conductivity values. As a result of the addition of conducting salt to the PIL membranes, the glass transition temperatures and the ionic conductivity values decreases. Nevertheless, PFG-NMR reveals a higher lithium-ion mobility for a sample with higher conducting salt content.

SUBMITTER: Lowe R

PROVIDER: S-EPMC7961940 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Structure-Property Relationship of Polymerized Ionic Liquids for Solid-State Electrolyte Membranes.

Löwe Robert R Hanemann Thomas T Zinkevich Tatiana T Hofmann Andreas A

Polymers 20210304 5

Eight new polymerized ammonium-based ionic liquids were prepared as thin membrane films and evaluated within the scope of their usage in lithium-ion batteries. The focus of this work is to get a better understanding of the influence of structural modifications of the monomers on the polymerized materials. Further, different concentrations of a lithium-ion conducting salt were applied in order to receive an optimized combination of monomer structure and lithium salt concentration. It was found th ...[more]

PMID: 33806668

Similar Datasets

UV-Polymerized Vinylimidazolium Ionic Liquids for Permselective Membranes.

Project description:Ionic liquids are highly charged compounds with increasing applications in material science. A universal approach to synthesize free-standing, vinylalkylimidazolium bromide-containing membranes with an adjustable thickness is presented. By the variation of alkyl side chains, membrane characteristics such as flux and mechanical properties can be adjusted. The simultaneous use of different ionic liquids (ILs) in the synthesis can also improve the membrane properties. In separation application, these charged materials allowed us to retain charged sugars, such as calcium gluconate, by up to 95%, while similar neutral compounds such as glucose passed the membrane. An analysis of the surface conditions using atomic force microscopy (AFM) confirmed the experimental data and explains the decreasing permeance and increased retention of the charged sugars.

| S-EPMC7692284 | biostudies-literature

Influence of Tethered Ions on Electric Polarization and Electrorheological Property of Polymerized Ionic Liquids.

Project description:Polymerized ionic liquids (PILs) show potential to be used as new water-free polyelectrolyte-based electrorheological (ER) material. To direct ER material design at the molecular level, unveiling structure-property relationships is essential. While a few studies compare the mobile ions in PILs there is still a limited understanding of how the structure of tethered counterions on backbone influences ER property. In this study, three PILs with same mobile anions but different tethered countercations (e.g., poly(dimethyldiallylammonium) P[DADMA]+, poly(benzylethyl) trimethylammonium P[VBTMA]+, and poly(1-ethyl-4-vinylimidazolium hexafluorophosphate) P[C2VIm]+) are prepared and the influence of tethered countercations on the ER property of PILs is investigated. It shows that among these PILs, P[DADMA]+ PILs have the strongest ER property and P[C2VIm]+ PILs have the weakest one. By combining dielectric spectra analysis with DFT calculation and activation energy measurement, it can clarify that the influence of tethered counterions on ER property is mainly associated with ion-pair interaction energy that is affecting ionic conductivity and interfacial polarization induced by ion motion. P[DADMA]+ has the smallest ion-pair interaction energy with mobile ions, which can result in the highest ionic conductivity and the fastest interfacial polarization rate for its strongest ER property.

| S-EPMC7356505 | biostudies-literature

CO2/CH4 Separation in Amino Acid Ionic Liquids, Polymerized Ionic Liquids, and Mixed Matrix Membranes.

Project description:The ability to efficiently separate CO2 from other light gases using membrane technology has received a great deal of attention due to its importance in applications such as improving the efficiency of natural gas and reducing greenhouse gas emissions. A wide range of materials has been employed for the fabrication of membranes. This paper highlights the work carried out to develop novel advanced membranes with improved separation performance. We integrated a polymerizable and amino acid ionic liquid (AAIL) with zeolite to fabricate mixed matrix membranes (MMMs). The MMMs were prepared with (vinylbenzyl)trimethylammonium chloride [VBTMA][Cl] and (vinylbenzyl)trimethylammonium glycine [VBTMA][Gly] as the polymeric support with 5 wt% zeolite particles, and varying concentrations of 1-butyl-3-methylimidazolium glycine, [BMIM][Gly] (5-20 wt%) blended together. The membranes were fabricated through photopolymerization. The extent of polymerization was confirmed using FTIR. FESEM confirmed the membranes formed are dense in structure. The thermal properties of the membranes were measured using TGA and DSC. CO2 and CH4 permeation was studied at room temperature and with a feed side pressure of 2 bar. [VBTMA][Gly]-based membranes recorded higher CO2 permeability and CO2/CH4 selectivity compared to [VBTMA][Cl]-based membranes due to the facilitated transport of CO2. The best performing membrane Gly-Gly-20 recorded permeance of 4.17 GPU and ideal selectivity of 5.49.

| S-EPMC10974021 | biostudies-literature

A Super-Ionic Solid-State Block Copolymer Electrolyte.

Project description:Polymer solid-state electrolytes offer great promise for battery materials with high energy density, mechanical stability, and improved safety. However, their low ion conductivities have so far limited their potential applications. Here, it is shown for poly(ethylene oxide) block copolymers that the super-stoichiometric addition of lithium bis(trifluoromethanesulfonyl) imide (LiTFSI) as lithium salt leads to the formation of a crystalline PEO block copolymer phase with exceptionally high ion conductivities and low activation energies. The addition of LiTFSI further induces block copolymer phase transitions into bi-continuous Fddd and gyroid network morphologies, providing continuous 3D conduction pathways. Both effects lead to solid-state block copolymer electrolyte membranes with ion conductivities of up to 1·10-1 S cm-1 at 90 °C, decreasing only moderately to 4·10-2 S cm-1 at room temperature, and to >1·10-3 S cm-1 at -20 °C, corresponding to activation energies as low as 0.19 eV. The co-crystallization of PEO and LiTFSI with ether and carbonate solvents is observed to play a key role to realize a super-ionic conduction mechanism. The discovery of PEO super-ionic conductivity at high lithium concentrations opens a new pathway for fabrication of solid polymer electrolyte membranes with sufficiently high ion conductivities over a broad temperature range with widespread applications in electrical devices.

| S-EPMC11618730 | biostudies-literature

Lithium Salt Catalyzed Ring-Opening Polymerized Solid-State Electrolyte with Comparable Ionic Conductivity and Better Interface Compatibility for Li-Ion Batteries.

Project description:Rechargeable lithium-ion batteries have drawn extensive attention owing to increasing demands in applications from portable electronic devices to energy storage systems. In situ polymerization is considered one of the most promising approaches for enabling interfacial issues and improving compatibility between electrolytes and electrodes in batteries. Herein, we observed in situ thermally induced electrolytes based on an oxetane group with LiFSI as an initiator, and investigated structural characteristics, physicochemical properties, contacting interface, and electrochemical performances of as-prepared SPEs with a variety of technologies, such as FTIR, 1H-NMR, FE-SEM, EIS, LSV, and chronoamperometry. The as-prepared SPEs exhibited good thermal stability (stable up to 210 °C), lower activation energy, and high ionic conductivity (>0.1 mS/cm) at 30 °C. Specifically, SPE-2.5 displayed a comparable ionic conductivity (1.3 mS/cm at 80 °C), better interfacial compatibility, and a high Li-ion transference number. The SPE-2.5 electrolyte had comparable coulombic efficiency with a half-cell configuration at 0.1 C for 50 cycles. Obtained results could provide the possibility of high ionic conductivity and good compatibility through in situ polymerization for the development of Li-ion batteries.

| S-EPMC8955661 | biostudies-literature

Capacitance of thin films containing polymerized ionic liquids.

Project description:Electrode-polymer interfaces dictate many of the properties of thin films such as capacitance, the electric field experienced by polymers, and charge transport. However, structure and dynamics of charged polymers near electrodes remain poorly understood, especially in the high concentration limit representative of the melts. To develop an understanding of electric field-induced transformations of electrode-polymer interfaces, we have studied electrified interfaces of an imidazolium-based polymerized ionic liquid (PolyIL) using combinations of broadband dielectric spectroscopy, specular neutron reflectivity, and simulations based on the Rayleigh's dissipation function formalism. Overall, we obtained the camel-shaped dependence of the capacitance on applied voltage, which originated from the responses of an adsorbed polymer layer to applied voltages. This work provides additional insights related to the effects of molecular weight in affecting structure and properties of electrode-polymer interfaces, which are essential for designing next-generation energy storage and harvesting devices.

| S-EPMC7319767 | biostudies-literature

Sulfide solid electrolyte with favorable mechanical property for all-solid-state lithium battery.

Project description:All-solid-state secondary batteries that employ inorganic solid electrolytes are desirable because they are potentially safer than conventional batteries. The ionic conductivities of solid electrolytes are currently attracting great attention. In addition to the conductivity, the mechanical properties of solid electrolytes are important for improving the energy density and cycle performance. However, the mechanical properties of sulfide electrolytes have not been clarified in detail. Here, we demonstrate the unique mechanical properties of sulfide electrolytes. Sulfide electrolytes show room temperature pressure sintering. Ionic materials with low bond energies and a highly covalent character, which is promising for achieving a high ionic conductivity, tend to be suitable for room-temperature processing. The Young's moduli of sulfide electrolytes were measured to be about 20 GPa, which is an intermediate value between those of typical oxides and organic polymers.

| S-EPMC3719077 | biostudies-literature

Insights into structure-property relationships in ionic liquids using cyclic perfluoroalkylsulfonylimides.

Project description:Room temperature ionic liquids of cyclic sulfonimide anions ncPFSI (ring size: n = 4-6) with the cations [EMIm]+ (1-ethyl-3-methylimidazolium), [BMIm]+ (1-butyl-3-methylimidazolium) and [BMPL]+ (BMPL = 1-butyl-1-methylpyrrolidinium) have been synthesized. Their solid-state structures have been elucidated by single-crystal X-ray diffraction and their physicochemical properties (thermal behaviour and stability, dynamic viscosity and specific conductivity) have been assessed. In addition, the ion diffusion was studied by pulsed field gradient stimulated echo (PFGSTE) NMR spectroscopy. The decisive influence of the ring size of the cyclic sulfonimide anions on the physicochemical properties of the ILs has been revealed. All ILs show different properties compared to those of the non-cyclic TFSI anion. While these differences are especially distinct for ILs with the very rigid 6cPFSI anion, the 5-membered ring anion 5cPFSI was found to result in ILs with relatively similar properties. The difference between the properties of the TFSI anion and the cyclic sulfonimide anions has been rationalized by the rigidity (conformational lock) of the cyclic sulfonimide anions. The comparison of selected IL properties was augmented by MD simulations. These highlight the importance of π+-π+ interactions between pairs of [EMIm]+ cations in the liquid phase. The π+-π+ interactions are evident for the solid state from the molecular structures of the [EMIm]+-ILs with the three cyclic imide anions determined by single-crystal X-ray diffraction.

| S-EPMC9945419 | biostudies-literature

In situ polymerized ionic liquids in polyester fiber composite membranes for detection of trace oil.

Project description:In situ trace detection on ultra-clean surfaces is an important technology. The polyester fiber (PF) was introduced to serve as the template, to which the ionic liquids were bonded by hydrogen bonding. Polymerized ionic liquids (PIL) in PF were formed by in situ polymerization with the azodiisobutyronitrile (AIBN) and IL. The trace oil on metal surfaces was enriched by the composite membrane based on similar compatibility principle. The absolute recovery of the trace oil ranged from 91%-99% using this composite membrane. In the extraction samples, desirable linear correlations were obtained for trace oil in the range of 1.25-20 mg/mL. It has been proven that a 1 cm2 PIL-PF composite membrane can effectively extract as little as 1 mg of lubricating oil on an ultra-clean metal surface of 0.1 m2 with the LOD of 0.9 mg/mL, making it a promising material for in situ detection of trace oil on metal surfaces.

| S-EPMC10206487 | biostudies-literature

Swelling and Diffusion in Polymerized Ionic Liquids-Based Hydrogels.

Project description:Hydrogels are one of the emerging classes of materials in current research. Besides their numerous applications in the medical sector as a drug delivery system or in tissue replacement, they are also suitable as irrigation components or as immobilization matrices in catalysis. For optimal application of these compounds, knowledge of the swelling properties and the diffusion mechanisms occurring in the gels is mandatory. This study is focused on hydrogels synthesized by radical polymerization of imidazolium-based ionic liquids. Both the swelling and diffusion behavior of these hydrogels were investigated via gravimetric swelling as well as sorption experiments implemented in water, ethanol, n-heptane, and tetrahydrofuran. In water and ethanol, strong swelling was observed while the transport mechanism deviated from Fickian-type behavior. By varying the counterion and the chain length of the cation, their influences on the processes were observed. The calculation of the diffusion coefficients delivered values in the range of 10-10 to 10-12 m2 s-1. The gravimetric results were supported by apparent diffusion coefficients measured through diffusion-weighted magnetic resonance imaging. A visualization of the water diffusion front within the hydrogel should help to further elucidate the diffusion processes in the imidazolium-based hydrogels.

| S-EPMC8199506 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data