Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Extreme Energy Dissipation via Material Evolution in Carbon Nanotube Mats.

ABSTRACT: Thin layered mats comprised of an interconnected meandering network of multiwall carbon nanotubes (MWCNT) are subjected to a hypersonic micro-projectile impact test. The mat morphology is highly compliant and while this leads to rather modest quasi-static mechanical properties, at the extreme strain rates and large strains resulting from ballistic impact, the MWCNT structure has the ability to reconfigure resulting in extraordinary kinetic energy (KE) absorption. The KE of the projectile is dissipated via frictional interactions, adiabatic heating, tube stretching, and ultimately fracture of taut tubes and the newly formed fibrils. The energy absorbed per unit mass of the film can range from 7-12 MJ kg^-1, much greater than any other material.

SUBMITTER: Hyon J

PROVIDER: S-EPMC7967058 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Extreme Energy Dissipation via Material Evolution in Carbon Nanotube Mats.

Hyon Jinho J Lawal Olawale O Thevamaran Ramathasan R Song Ye Eun YE Thomas Edwin L EL

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20210129 6

Thin layered mats comprised of an interconnected meandering network of multiwall carbon nanotubes (MWCNT) are subjected to a hypersonic micro-projectile impact test. The mat morphology is highly compliant and while this leads to rather modest quasi-static mechanical properties, at the extreme strain rates and large strains resulting from ballistic impact, the MWCNT structure has the ability to reconfigure resulting in extraordinary kinetic energy (KE) absorption. The KE of the projectile is diss ...[more]

PMID: 33747728

Similar Datasets

Field-Dependent Heat Dissipation of Carbon Nanotube Electric Currents.

Project description:We study heat dissipation of a multi-wall carbon nanotube (MWCNT) device fabricated from two crossed nanotubes on a SiNx substrate under the influence of a constant (DC) electric bias. By monitoring the temperature of the substrate, we observe negligible Joule heating within the nanotube lattice itself and instead heating occurs in the insulating substrate directly via a remote-scattering heating effect. Using finite element analysis, we estimate a remote heating parameter, β, as the ratio of the power dissipated directly in the substrate to the total power applied. The extracted parameters show two distinct bias ranges; a low bias regime where about 85% of the power is dissipated directly into the substrate and a high bias regime where β decreases, indicating the onset of traditional Joule heating within the nanotube. Analysis shows that this reduction is consistent with enhanced scattering of charge carriers by optical phonons within the nanotube. The results provide insights into heat dissipation mechanisms of Joule heated nanotube devices that are more complex than a simple heat dissipation mechanism dominated by acoustic phonons, which opens new possibilities for engineering nanoelectronics with improved thermal management.

| S-EPMC6658496 | biostudies-literature

Phonon transport assisted by inter-tube carbon displacements in carbon nanotube mats.

Project description:Thermal transport in carbon nanotube (CNT) mats, consisting of randomly networked multi-walled carbon nanotubes (MWNTs), is not as efficient as in an individual CNT because of the constrained tube-to-tube phonon transport. Through experiments and modeling, we discover that phonon transport in CNT mats is significantly improved by ion irradiation, which introduces inter-tube displacements, acting as stable point contacts between neighboring tubes. Inter-tube displacement-mediated phonon transport enhances conductivity, while inter-tube phonon-defect scattering reduces conductivity. At low ion irradiation fluence, inter-tube thermal transport enhancement leads to thermal conductivity increase by factor>5, while at high ion irradiation fluence point defects within tubes cause a decrease in thermal conductivity. Molecular dynamics simulations support the experimentally obtained results and the proposed mechanisms. Further conductivity enhancement in irradiated mats was obtained by post-irradiation heat treatment that removes majority of the defects within the tubes without affecting thermally stable inter-tube displacements.

| S-EPMC3784949 | biostudies-literature

Dissipation and energy propagation across scales in an active cytoskeletal material.

Project description:Living systems are intrinsically nonequilibrium: They use metabolically derived chemical energy to power their emergent dynamics and self-organization. A crucial driver of these dynamics is the cellular cytoskeleton, a defining example of an active material where the energy injected by molecular motors cascades across length scales, allowing the material to break the constraints of thermodynamic equilibrium and display emergent nonequilibrium dynamics only possible due to the constant influx of energy. Notwithstanding recent experimental advances in the use of local probes to quantify entropy production and the breaking of detailed balance, little is known about the energetics of active materials or how energy propagates from the molecular to emergent length scales. Here, we use a recently developed picowatt calorimeter to experimentally measure the energetics of an active microtubule gel that displays emergent large-scale flows. We find that only approximately one-billionth of the system's total energy consumption contributes to these emergent flows. We develop a chemical kinetics model that quantitatively captures how the system's total thermal dissipation varies with ATP and microtubule concentrations but that breaks down at high motor concentration, signaling an interference between motors. Finally, we estimate how energy losses accumulate across scales. Taken together, these results highlight energetic efficiency as a key consideration for the engineering of active materials and are a powerful step toward developing a nonequilibrium thermodynamics of living systems.

| S-EPMC10083585 | biostudies-literature

3D Printed Carbon Nanotube/Phenolic Composites for Thermal Dissipation and Electromagnetic Interference Shielding.

Project description:Here we demonstrate direct ink write (DIW) additive manufacturing of carbon nanotube (CNT)/phenolic composites with heat dissipation and excellent electromagnetic interference (EMI) shielding capabilities without curing-induced deformation. Such polymer composites are valuable for protecting electronic devices from overheating and electromagnetic interference. CNTs were used as a multifunctional nanofiller to improve electrical and thermal conductivity, printability, stability during curing, and EMI shielding performance of CNT/phenolic composites. Different CNT loadings, curing conditions, substrate types, and sample sizes were explored to minimize the negative effects of the byproducts released from the cross-linking reactions of phenolic on the printed shape integrity. At a CNT loading of 10 wt %, a slow curing cycle enables us to cure printed thin-walled CNT/phenolic composites with highly dense structures; such structures are impossible without a filler. Moreover, the electrical conductivity of the printed 10 wt % CNT/phenolic composites increased by orders of magnitude due to CNT percolation, while an improvement of 92% in thermal conductivity was achieved over the neat phenolic. EMI shielding effectiveness of the printed CNT/phenolic composites reaches 41.6 dB at the same CNT loading, offering a shielding efficiency of 99.99%. The results indicate that high CNT loading, a slow curing cycle, flexible substrates, and one thin sample dimension are the key factors to produce high-performance 3D-printed CNT/phenolic composites to address the overheating and EMI issues of modern electronic devices.

| S-EPMC11660157 | biostudies-literature

Influence of CNTRENE C100LM Carbon Nanotube Material on the Growth and Regulation of Escherichia coli

Project description:Influence of global gene expression of Escherichia coli when exposed to CNTRENE C100LM carbon nanotubes

2017-05-20 | GSE99042 | GEO

Polymeric Nanofiber-Carbon Nanotube Composite Mats as Fast-Equilibrium Passive Samplers for Polar Organic Contaminants.

Project description:To improve the performance of polymeric electrospun nanofiber mats (ENMs) for equilibrium passive sampling applications in water, we integrated two types of multiwalled carbon nanotubes (CNTs; with and without surface carboxyl groups) into polyacrylonitrile (PAN) and polystyrene (PS) ENMs. For 11 polar and moderately hydrophobic compounds (-0.07 ≤ logKOW ≤ 3.13), 90% of equilibrium uptake was achieved in under 0.8 days (t90% values) in nonmixed ENM-CNT systems. Sorption capacity of ENM-CNTs was between 2- and 50-fold greater than pure polymer ENMs, with equilibrium partition coefficients (KENM-W values) ranging from 1.4 to 3.1 log units (L/kg) depending on polymer type (hydrophilic PAN or hydrophobic PS), CNT loading (i.e., values increased with weight percent (wt %) of CNTs), and CNT type (i.e., greater uptake with carboxylated CNTs composites). During field deployment at Muddy Creek in North Liberty, Iowa, optimal ENM-CNTs (PAN with 20 wt % carboxylated CNTs) yielded atrazine concentrations in surface water with a 40% difference relative to analysis of a same-day grab sample. We also observed a mean percent difference of 30 (±20)% when comparing ENM-CNT sampler results to grab sample data collected within 1 week of deployment. With their rapid, high capacity uptake and small material footprint, ENM-CNT equilibrium passive samplers represent a promising alternative to complement traditional integrative passive samplers while offering convenience over large volume grab sampling.

| S-EPMC7665838 | biostudies-literature

Modulating Interfacial Energy Dissipation via Potential-Controlled Ion Trapping.

Project description:As a metal (gold) surface at a given, but variable potential slides past a dielectric (mica) surface at a fixed charge, across aqueous salt solutions, two distinct dissipation regimes may be identified. In regime I, when the gold potential is such that counterions are expelled from between the surfaces, which then come to adhesive contact, the frictional dissipation is high, with coefficient of friction μ ≈ 0.8-0.9. In regime II, when hydrated counterions are trapped between the compressed surfaces, hydration lubrication is active and friction is much lower, μ = 0.05 ± 0.03. Moreover, the dissipation regime as the surfaces contact is largely retained even when the metal potential changes to the other regime, attributed to the slow kinetics of counterion expulsion from or penetration into the subnanometer intersurface gap. Our results indicate how frictional dissipation between such a conducting/nonconducting couple may be modulated by the potential applied to the metal.

| S-EPMC7898939 | biostudies-literature

A material dynamically enhancing both load-bearing and energy dissipation capability under cyclic loading.

Project description:Material properties gradually degrade under cyclic loading, leading to catastrophic failure. It results in large costs for inspection, maintenance, and downtime. Besides, materials require combinations of performance such as load bearing and energy dissipation. However, improving one performance of a material often sacrifices another performance, making it difficult to create materials with optimal performance profiles. Here we report a liquid-infused porous piezoelectric scaffold (LIPPS) that simultaneously enhances its load-bearing and energy dissipation capability under cyclic loading. For example, after 12 million loading cycles, LIPPS increases its modulus by 3600% and hysteresis by 3000%. From a CT study, this behavior is attributed to the self-recoverable mineralization under mechanical loading. Moreover, LIPPS shows a reprogrammable stiffness distribution based on the loading distribution, which enables the material to generate multiple shapes by self-folding. Our findings can contribute toward unprecedented opportunities in soft robotics, vehicles, infrastructure, and tissue engineering and contribute to the new paradigm of material selection with improved resilience and sustainability.

| S-EPMC11804925 | biostudies-literature

Evolution of Electronic Circuits using Carbon Nanotube Composites.

Project description:Evolution-in-materio concerns the computer controlled manipulation of material systems using external stimuli to train or evolve the material to perform a useful function. In this paper we demonstrate the evolution of a disordered composite material, using voltages as the external stimuli, into a form where a simple computational problem can be solved. The material consists of single-walled carbon nanotubes suspended in liquid crystal; the nanotubes act as a conductive network, with the liquid crystal providing a host medium to allow the conductive network to reorganise when voltages are applied. We show that the application of electric fields under computer control results in a significant change in the material morphology, favouring the solution to a classification task.

| S-EPMC4997311 | biostudies-literature

Ultra-Tough Self-Healing Hydrogel via Hierarchical Energy Associative Dissipation.

Project description:Owing to high water content and homogeneous texture, conventional hydrogels hardly reach satisfactory mechanical performance. Tensile-resistant groups and structural heterogeneity are employed to fabricate tough hydrogels. However, those techniques significantly increase the complexity and cost of material synthesis, and have only limited applicability. Here, it is shown that ultra-tough hydrogels can be obtained via a unique hierarchical architecture composed of chemically coupled self-assembly units. The associative energy dissipation among them may be rationally engineered to yield libraries of tough gels with self-healing capability. Tunable tensile strength, fracture strain, and toughness of up to 19.6 MPa, 20 000%, and 135.7 MJ cm⁻3 are achieved, all of which exceed the best known records. The results demonstrate a universal strategy to prepare desired ultra-tough hydrogels in predictable and controllable manners.

| S-EPMC10520617 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data