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Formal Enone α-Arylation via I(III)-Mediated Aryl Migration/Elimination.

ABSTRACT: A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones.

SUBMITTER: Martins BS

PROVIDER: S-EPMC7985840 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature

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Formal Enone α-Arylation via I(III)-Mediated Aryl Migration/Elimination.

Martins Bruna S BS Kaiser Daniel D Bauer Adriano A Tiefenbrunner Irmgard I Maulide Nuno N

Organic letters 20210226 6

A formal enone α-arylation is described. This metal-free transformation relies on the I(III)-mediated skeletal reorganization of silyl enol ethers and features mild conditions, good yields, and high stereoselectivities for β-substituted enones. ...[more]

PMID: 33635665

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