Selective Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran by Visible Light-Driven Photocatalysis over In Situ Substrate-Sensitized Titania.

ABSTRACT: Solar energy-driven processes for biomass valorization are priority for the growing industrialized society. To address this challenge, efficient visible light-active photocatalyst for the selective oxidation of biomass-derived platform chemical is highly desirable. Herein, selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF) was achieved by visible light-driven photocatalysis over titania. Pristine titania is photocatalytically inactive under visible light, so an unconventional approach was employed for the visible light (λ=515 nm) sensitization of titania via a formation of a visible light-absorbing complex of HMF (substrate) on the titania surface. Surface-complexation of HMF on titania mediated ligand-to-metal charge transfer (LMCT) under visible light, which

SUBMITTER: Khan A 

PROVIDER: S-EPMC7986172 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature