High-Pressure High-Temperature Synthesis of Mixed Nitridosilicatephosphates and Luminescence of AESiP₃ N₇ :Eu²⁺ (AE=Sr, Ba).

ABSTRACT: Tetrahedra-based nitrides with network structures have emerged as versatile materials with a broad spectrum of properties and applications. Both nitridosilicates and nitridophosphates are well-known examples of such nitrides that upon doping with Eu²⁺ exhibit intriguing luminescence properties, which makes them attractive for applications. Nitridosilicates and nitridophosphates show manifold structural variability; however, no mixed nitridosilicatephosphates except SiPN₃ and SiP2N4NH have been described so far. The compounds AESiP₃ N₇ (AE=Sr, Ba) were synthesized by a high-pressure high-temperature approach using the multianvil technique (8 GPa, 1400-1700 °C) starting from the respective alkaline earth azides and the binary nitrides P₃ N₅ and Si₃ N₄ . The latter were activated by NH₄ F, probably acting as a mineralizing agent. SrSiP₃ N₇ and BaSiP₃ N₇ were obtained as single crystals. They crystallized in the barylite-1O (M=Sr) and barylite-2O structure types (M=Ba), respectively, with P and Si being occupationally disordered. Cation disorder was further supported by solid-state NMR spectroscopy and energy-dispersive X-ray spectroscopy (EDX) mapping of BaSiP₃ N₇ with atomic resolution. Upon doping with Eu²⁺ , both compounds showed blue emission under UV excitation.

SUBMITTER: Eisenburger L 

PROVIDER: S-EPMC7986791 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature