Efficient and selective catalytic hydroxylation of unsaturated plant oils: a novel method for producing anti-pathogens.

ABSTRACT: With the increasing demand for antimicrobial agents and the spread of antibiotic resistance in pathogens, the exploitation of plant oils to partly replace antibiotic emerges as an important source of fine chemicals, functional food utility and pharmaceutical industries. This work introduces a novel catalytic method of plant oils hydroxylation by Fe(III) citrate monohydrate (Fe³⁺-cit.)/Na₂S₂O₈ catalyst. Methyl (9Z,12Z)-octadecadienoate (ML) was selected as an example of vegetable oils hydroxylation to its hydroxy-conjugated derivatives (CHML) in the presence of a new complex of Fe(II)-species. Methyl 9,12-di-hydroxyoctadecanoate 1, methyl-9-hydroxyoctadecanoate 2 and methyl (10E,12E)-octadecanoate 3 mixtures is produced under optimized condition w

SUBMITTER: Senan AM 

PROVIDER: S-EPMC8008645 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature