Hf Deposition Stabilizes the Surface Chemistry of Perovskite Manganite Oxide.

ABSTRACT: Stable composition and catalytic activity of surfaces are among the key requirements for materials employed in energy storage and conversion devices, such as solid oxide fuel cells (SOFCs). Perovskite oxides that serve as cathode in SOFCs suffer from segregation of the aliovalent substitutional cations and the formation of an inert, non-conductive phase at the surface. Here, we demonstrate that the surface of the state-of-the-art SOFC cathode material La_0.8Sr_0.2MnO₃ (LSM) is stabilized against the segregation of Sr at high temperature by submonolayer coverages of Hf. The Hf is vapor-deposited onto the LSM thin film surface by e-beam evaporation. Using in situ near-ambient pressure X-ray photoelectron spectroscopy (NAP-XPS), we analyze the surface com

SUBMITTER: Bliem R 

PROVIDER: S-EPMC8016110 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature