Ontology highlight
ABSTRACT:
SUBMITTER: Ament K
PROVIDER: S-EPMC8016112 | biostudies-literature | 2021 Mar
REPOSITORIES: biostudies-literature
Ament Kevin K Wagner Daniel R DR Götsch Thomas T Kikuchi Takayuki T Kröhnert Jutta J Trunschke Annette A Lunkenbein Thomas T Sasaki Takayoshi T Breu Josef J
ACS catalysis 20210215 5
As atomically thin oxide layers deposited on flat (noble) metal surfaces have been proven to have a significant influence on the electronic structure and thus the catalytic activity of the metal, we sought to mimic this architecture at the bulk scale. This could be achieved by intercalating small positively charged Pd nanoparticles of size 3.8 nm into a nematic liquid crystalline phase of lepidocrocite-type layered titanate. Upon intercalation the galleries collapsed and Pd nanoparticles were ca ...[more]