Experimental and Theoretical Study of the OH-Initiated Degradation of Piperazine under Simulated Atmospheric Conditions.

ABSTRACT: The OH-initiated photo-oxidation of piperazine and 1-nitropiperazine as well as the photolysis of 1-nitrosopiperazine were investigated in a large atmospheric simulation chamber. The rate coefficient for the reaction of piperazine with OH radicals was determined by the relative rate method to be k_{OH-piperazine} = (2.8 ± 0.6) × 10^-10 cm³ molecule^-1 s^-1 at 307 ± 2 K and 1014 ± 2 hPa. Product studies showed the piperazine + OH reaction to proceed both via C-H and N-H abstraction, resulting in the formation of 1,2,3,6-tetrahydropyrazine as the major product and in 1-nitropiperazine and 1-nitrosopiperazine as minor products. The branching in the piperazinyl radical reactions with NO, NO₂, and O₂ was obtained from

SUBMITTER: Tan W 

PROVIDER: S-EPMC8021224 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature