Creating Ferromagnetic Insulating La_0.9Ba_0.1MnO₃ Thin Films by Tuning Lateral Coherence Length.

ABSTRACT: In this work, heteroepitaxial vertically aligned nanocomposite (VAN) La_0.9Ba_0.1MnO₃ (LBMO)-CeO₂ films are engineered to produce ferromagnetic insulating (FMI) films. From combined X-ray photoelectron spectroscopy, X-ray diffraction, and electron microscopy, the elimination of the insulator-metal (I-M) transition is shown to result from the creation of very small lateral coherence lengths (with the corresponding lateral size ∼ 3 nm (∼7 u.c.)) in the LBMO matrix, achieved by engineering a high density of CeO₂ nanocolumns in the matrix. The small lateral coherence length leads to a shift in the valence band maximum and reduction of the double exchange (DE) coupling. There is no "dead layer" effect at the smallest achieved lateral coherenc

SUBMITTER: Yun C 

PROVIDER: S-EPMC8023513 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature