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Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data.

ABSTRACT: A simple corresponding state-based correlation, whose analytical expression contains just one term with an exponential function, is proposed to calculate the surface tension of 36 silanes, 29 carboxylic acids, and 81 refrigerants as a function of temperature. This correlation only requires critical temperature, maximum value of surface tension, and its corresponding temperature in the DIPPR database as inputs for each liquid considered. The correlation allows us to calculate the accepted DIPPR data for silanes with a mean absolute average deviation (AAD) of 2.75%, 2.42% for acids, and 3.32% for refrigerants. Moreover, it gives AADs below 3% for 99 fluids. The mean deviation for the 146 fluids is 3.0%, which is practically equal to the results obtained when two terms are used in the analytical expression.

SUBMITTER: Yang S

PROVIDER: S-EPMC8047697 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Surface Tension for Silanes, Refrigerants, and Carboxylic Acids: Simple Corresponding State Correlations versus DIPPR Data.

Yang Shangguo S Tian Jianxiang J Jiang Hua H Mulero Ángel Á Cachadiña Isidro I

ACS omega 20210331 14

A simple corresponding state-based correlation, whose analytical expression contains just one term with an exponential function, is proposed to calculate the surface tension of 36 silanes, 29 carboxylic acids, and 81 refrigerants as a function of temperature. This correlation only requires critical temperature, maximum value of surface tension, and its corresponding temperature in the DIPPR database as inputs for each liquid considered. The correlation allows us to calculate the accepted DIPPR d ...[more]

PMID: 33869974

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