Tunable Negative Poisson's Ratio in Van der Waals Superlattice.

ABSTRACT: Negative Poisson's ratio (NPR) materials are functional and mechanical metamaterials that shrink (expand) longitudinally after being compressed (stretched) laterally. By using first-principles calculations, we found that Poisson's ratio can be tuned from near zero to negative by different stacking modes in van der Waals (vdW) graphene/hexagonal boron nitride (G/h-BN) superlattice. We attribute the NPR effect to the interaction of p _z orbitals between the interfacial layers. Furthermore, a parameter calculated by analyzing the electronic band structure, namely, distance-dependent hopping integral, is used to describe the intensity of this interaction. We believe that this mechanism is not only applicable to G/h-BN superlattice but can also explain and

SUBMITTER: Li X 

PROVIDER: S-EPMC8054987 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature