Structure of Polymer-Grafted Nanoparticle Melts.

ABSTRACT: The structure of neat melts of polymer-grafted nanoparticles (GNPs) is studied via coarse-grained molecular dynamics simulations. We systematically vary the degree of polymerization and grafting density at fixed nanoparticle (NP) radius and study in detail the shape and size of the GNP coronas. For sufficiently high grafting density, chain sections close to the NP core are extended and form a dry layer. Further away from the NP, there is an interpenetration layer, where the polymer coronas of neighboring GNPs overlap and the chain sections have almost unperturbed conformations. To better understand this partitioning, we develop a two-layer model, representing the grafted polymer around an NP by spherical dry and interpenetration layers. This model quantitatively predicts that the th

SUBMITTER: Midya J 

PROVIDER: S-EPMC8056455 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature