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Vinyl-Functionalized Janus Ring Siloxane: Potential Precursors to Hybrid Functional Materials.

ABSTRACT: A vinyl-functionalized all-cis-tetrasiloxycyclotetrasiloxane [ViSi(OSiMe2H)O]4 (Vi = vinyl group) Janus precursor was prepared from potassium cyclotetrasiloxane silanolate. The Janus precursor was selectively modified at its dimethylhydrosilyl groups [-SiMe2H] via the Piers-Rubinsztajn reaction to obtain a family of new tetravinyl-substituted Janus rings [ViSi(OR')O]4 containing various functional groups in moderate yields. Remarkably, the tetravinyl groups on the structure remained intact after modification by the Piers-Rubinsztajn reaction. Since these synthesized compounds possess multiple functional groups (up to eight per molecule), they are potential precursors for advanced hybrid organic-inorganic functional materials.

SUBMITTER: Chaiprasert T

PROVIDER: S-EPMC8073502 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature

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Vinyl-Functionalized Janus Ring Siloxane: Potential Precursors to Hybrid Functional Materials.

Chaiprasert Thanawat T Liu Yujia Y Takeda Nobuhiro N Unno Masafumi M

Materials (Basel, Switzerland) 20210416 8

A vinyl-functionalized all-cis-tetrasiloxycyclotetrasiloxane [ViSi(OSiMe2H)O]4 (Vi = vinyl group) Janus precursor was prepared from potassium cyclotetrasiloxane silanolate. The Janus precursor was selectively modified at its dimethylhydrosilyl groups [-SiMe2H] via the Piers-Rubinsztajn reaction to obtain a family of new tetravinyl-substituted Janus rings [ViSi(OR')O]4 containing various functional groups in moderate yields. Remarkably, the tetra ...[more]

PMID: 33923699

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