Multiscale analysis of the hydrate based carbon capture from gas mixtures containing carbon dioxide.

ABSTRACT: To reveal the kinetic performance of gas molecules in hydrate growth, hydrate formation from pure CO₂, flue gas, and biogas was measured using in-situ Raman and macroscopic methods at 271.6 K. In the in-situ Raman measurements, Raman peaks of gases in the hydrate phase were characterised and normalised by taking the water bands from 2800 to 3800 cm^-1 as a reference, whose line shapes were not found to have a noticeable change in the conversion from Ih ice to sI hydrate. The hydrate growth was suggested to start with the formation of unsaturated hydrate nuclei followed by gas adsorption. In hydrate formed from all tested gases, CO₂ concentrations in hydrate nuclei were found to be 23-33% of the saturation state. In the flue gas system, the N₂ conc

SUBMITTER: Zhou X 

PROVIDER: S-EPMC8080785 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature