Mechanically compliant single crystals of a stable organic radical.

ABSTRACT: Mechanically compliant organic crystals are the foundation of the development of future flexible, light-weight single-crystal electronics, and this requires reversibly deformable crystalline organic materials with permanent magnetism. Here, we report and characterize the first instance of a plastically bendable single crystal of a permanent organic radical, 4-(4'-cyano-2',3',4',5'-tetrafluorophenyl)-1,2,3,5-dithiadiazolyl. The weak interactions between the radicals render single crystals of the β phase of this material exceedingly soft, and the S-N interactions facilitate plastic bending. EPR imaging of a bent single crystal reveals the effect of deformation on the three-dimensional spin density of the crystal. The unusual mechanical compliance of this material opens prospects for explorat

SUBMITTER: Commins P 

PROVIDER: S-EPMC8098752 | biostudies-literature | 2021 Mar

REPOSITORIES: biostudies-literature