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Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces.

ABSTRACT: We designed and synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The ligands effectively bind in at least a tridentate fashion at low surface coverage. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates.

SUBMITTER: Nemat SJ

PROVIDER: S-EPMC8112235 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature

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Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces.

Nemat Suren J SJ Van den Eynden Dietger D Deblock Loren L Heilmann Michael M Köster Jesper M JM Parvizian Mahsa M Tiefenbacher Konrad K De Roo Jonathan J

Chemical communications (Cambridge, England) 20210501 38

We designed and synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The ligands effectively bind in at least a tridentate fashion at low surface coverage. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates. ...[more]

PMID: 33977984

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