Confinement effects and acid strength in zeolites.

ABSTRACT: Chemical reactivity and sorption in zeolites are coupled to confinement and-to a lesser extent-to the acid strength of Brønsted acid sites (BAS). In presence of water the zeolite Brønsted acid sites eventually convert into hydronium ions. The gradual transition from zeolite Brønsted acid sites to hydronium ions in zeolites of varying pore size is examined by ab initio molecular dynamics combined with enhanced sampling based on Well-Tempered Metadynamics and a recently developed set of collective variables. While at low water content (1-2 water/BAS) the acidic protons prefer to be shared between zeolites and water, higher water contents (n > 2) invariably lead to solvation of the protons within a localized water cluster adjacent to the BAS. At low water loadings the standard free energy of

SUBMITTER: Grifoni E 

PROVIDER: S-EPMC8113345 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature