Coherent vibrational dynamics reveals lattice anharmonicity in organic-inorganic halide perovskite nanocrystals.

ABSTRACT: The halide ions of organic-inorganic hybrid perovskites can strongly influence the interaction between the central organic moiety and the inorganic metal halide octahedral units and thus their lattice vibrations. Here, we report the halide-ion-dependent vibrational coherences in formamidinium lead halide (FAPbX₃, X = Br, I) perovskite nanocrystals (PNCs) via the combination of femtosecond pump-probe spectroscopy and density functional theory calculations. We find that the FAPbX₃ PNCs generate halide-dependent coherent vibronic wave packets upon above-bandgap non-resonant excitation. More importantly, we observe several higher harmonics of the fundamental modes for FAPbI₃ PNCs as compared to FAPbBr₃ PNCs. This is likely due to the weaker interacti

SUBMITTER: Debnath T 

PROVIDER: S-EPMC8113605 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature