Ubiquitous atmospheric production of organic acids mediated by cloud droplets.

ABSTRACT: Atmospheric acidity is increasingly determined by carbon dioxide and organic acids^1-3. Among the latter, formic acid facilitates the nucleation of cloud droplets⁴ and contributes to the acidity of clouds and rainwater^1,5. At present, chemistry-climate models greatly underestimate the atmospheric burden of formic acid, because key processes related to its sources and sinks remain poorly understood^2,6-9. Here we present atmospheric chamber experiments that show that formaldehyde is efficiently converted to gaseous formic acid via a multiphase pathway that involves its hydrated form, methanediol. In warm cloud droplets, methanediol undergoes fast outgassing but slow dehydration. Using a chemistry-climate model, we estimate that the gas-phase oxidati

SUBMITTER: Franco B 

PROVIDER: S-EPMC8116209 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature