Design and Characterization of Electrochemical Sensor for the Determination of Mercury(II) Ion in Real Samples Based upon a New Schiff Base Derivative as an Ionophore.

ABSTRACT: The present paper provides a description of the design, characterization, and use of a Hg2+ selective electrode (Hg2+-SE) for the determination of Hg2+ at ultra-traces levels in a variety of real samples. The ionophore in the proposed electrode is a new Schiff base, namely 4-bromo-2-[(4-methoxyphenylimino)methyl]phenol (BMPMP). All factors affecting electrode response including polymeric membrane composition, concentration of internal solution, pH sample solution, and response time were optimized. The optimum response of our electrode was obtained with the following polymeric membrane composition (% w/w): PVC, 32; o-NPOE, 64.5; BMPMP, 2 and NaTPB, 1.5. The potentiometric response of Hg2+-SE towards Hg2+ ion was linear in the wide range of concentrations (9.33 × 10-8-3.98 × 10-3 molL-1), wh

SUBMITTER: Alharthi SS 

PROVIDER: S-EPMC8123339 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature